Abstract

The effects of substituents in the meta and para positions of benzylic radicals on the α- and β-hydrogen hyperfine coupling constants (hfc’s) are discussed. The relationship between hfc and radical stabilization energy is also described. The development of the σ•α substituent parameter scale is reviewed; and, examples ofαthe application of the σ•α parameters in Hammett type linear free-energy corre lationsα are given.

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