The effect of slip casting and spark plasma sintering (SPS) temperature on the transparency of MgAl2O4 spinel

Abstract

MgAl2O4 bulk samples were fabricated by two different approaches to investigate the effect of slip casting and sintering temperature on their transparency. Three MgAl2O4 samples containing 1wt% LiF, as the sintering aid, were prepared by the spark plasma sintering process (SPS) at 1400°C and 1500°C, under 100MPa, for 15min. Also, another MgAl2O4 sample was prepared by slip casting followed by SPS under similar conditions. It was observed that utilizing slip casting led to more transparency (10% in the visible region and 20% in the IR region) due to the more homogeneous structure. It was also observed that by reducing the SPS temperature from 1500°C to 1400°C, the transparency increased (20% in the IR region) because of the lower grain growth rate at the lower temperature.