The effect of sintering aids on BaCe0·7Zr0·1Y0.1Yb0.1O3-δ as the electrolyte of proton-conducting solid oxide electrolysis cells

Abstract

Proton-conducting solid oxide electrolysis cells (H-SOECs) are attracting attentions of researchers due to their unique advantages. The proton-conducting material BaCe0·7Zr0·1Y0.1Yb0.1O3-δ (BZCYYb) has both the advantages of barium ceria-based and barium zirconate-based materials. BZCYYb material usually is synthesized by solid-state reaction (SSR) method, hence the densification of this electrolyte material is the key to restrict the application of H-SOECs. In this paper, effects of adding 1 wt% of different sintering aids (NiO, CuO, ZnO) to BZCYYb on the grain size and the conductivity are investigated. After adding 1 wt% of NiO and CuO sintering aids, BZCYYb electrolyte achieves ideal density. The electrical conductivity of four samples (BZCYYb without adding sintering aid, BZCYYb with 1 wt% NiO, CuO, ZnO, respectively) is tested under different steam concentrations of air, nitrogen, hydrogen, and nitrogen-hydrogen mixture. The conductivity increased after the sintering aid is added. With the increase of steam concentration, the conductivity decreased slightly and then increased due to electron holes under oxygen atmosphere with steam at high temperature. In other atmospheres, the conductivity increases with the steam concentration. In the atmosphere of 20 vol% H2O-Air and H2, the conductivity of the BZCYYb samples with 1 wt% CuO is about 1.087 × 10−2 S cm−1 and 9.02 × 10−3 S cm−1 at 650 °C, and the conductivity of the BZCYYb samples with 1 wt% NiO is 1.277 × 10−2 S cm−1 and 8.24 × 10−3 S cm−1, respectively. However, compared with NiO, CuO has advantages in promoting hydration reaction and proton conduction of BZCYYb electrolyte.