Abstract

Abstract The present paper describes experimental and theoretical aspects of the effective thermal conductivity, electrical conductivity, and viscosity of nanofluids. The thermal conductivity, electrical conductivity, and viscosity of nanofluids increase with the nanoparticle volume fraction. The nanofluid was prepared by synthesizing Al2O3 and Ag nanoparticles using microwave-assisted chemical precipitation method and then dispersed in distilled water using a sonicator. Water nanofluid with nominal diameters of 20 and 40 nm at various volume concentrations (0.25% to 5%) at a temperature of 15°C was used for the investigation. The thermal conductivity, electrical conductivity, and viscosity of nanofluids were measured, and it was found that the viscosity and electrical conductivity increase is substantially higher than the increase in thermal conductivity. The pure base fluid thermal conductivity displayed a Newtonian behavior at 15°C; it transformed to a non-Newtonian fluid with the addition of a small amount of nanoparticles φ > 3%.

Highlights

  • Experimental detailsNanocomposites are materials of considerable interest because of their unique design and excellent properties

  • Compared to NiO, NiO/CoPc shows very good absorption in the range 300–750 nm. This corresponds to the B band (Sorret band) and Q band which are characteristic of metal phthalocyanines

  • NiO/CoPc nanocomposite is synthesized by simple solvent evaporation method

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Summary

Introduction

Nanocomposites are materials of considerable interest because of their unique design and excellent properties. Phthalocyanines are p-type organic semiconductors with high stability, having wide range of applications from medicine to microelectronics [2].Out of these; metal phthalocyanines (M.Pc) have invited attention due to their good thermal and chemical stability, photoconductivity and semi-conducting nature. Their thermal and chemical stability are important properties that make them suitable for electrochemical sensors [3]. The thermal, structural and optical properties of the nanocomposite are studied and compared with that of NiO nanoparticles. This is the first report on the synthesis and characterization of NiO/CoPc nanocomposites. PL spectra of the samples at room temperature are measured using a Fluoromax 3 spectrophotometer

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