The effect of silica nanoparticles on the dustiness of industrial powders

Abstract

Industrial powders are prompt to be airborne during processing. High dustiness levels may cause process complications like cross-contamination, product loss and filter clogging while increasing the risk of inhalation, dust explosion and fire. Thus, dustiness is often associated with occupational exposure. Despite this, powder products are usually composed of multiple ingredients with silica nanoparticles (S-NP) systematically added to ease their handling. Surprisingly, the relationship between dustiness and product formulation has not been commonly studied. This work investigates the influence of S-NP, SIPERNAT D10 (SD10), on the dustiness of four industrial powders–Avicel PH102, wheat flour, joint filler, and glass beads–using two standard methods: the rotating drum (EN 15051–2) and the vortex shaker (EN 17199–5). Our results show that the dustiness of mixtures powder + SD10 are statistically higher than those of the powder alone and can reach the levels of SD10. TEM micrographs from airborne particles collected in the vortex shaker showed that SD10 detached from the surface of the powder during aerosolisation, emitting nanometric dust; adding SD10 increases the potential for inhalation exposure during industrial processing and handling. Surface energy analysis by inverse gas chromatography (IGC) leads us to conclude that stronger powder-to-SD10 interactions result in less dust emission.