Abstract
The objective of this study was to investigate the effect of shear flow on the percolation concentration (cp) for solutions of fibrillar protein assemblies. Theoretical calculations were performed to obtain cp versus Peclet number. They were based on a random contact model for rodlike particles, making use of a shear dependent excluded volume per fibril. We found cp to increase with increasing Peclet number. Results of flow birefringence measurements were used to obtain the rotational diffusion coefficient at cp, which enables one to transform the theoretically obtained cp(Pe) into a prediction for cp versus shear rate. This prediction was used to fit viscosity measurements as a function of shear rate, near the percolation threshold. A satisfactory fit was found indicating that the percolation threshold, cp, as function of shear rate can be predicted by combining theory and optical measurements.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
