The effect of physical compatibilization and dynamic vulcanization on the properties of thermoplastic vulcanizates derived from polypropylene and natural rubber blends

Abstract

This interesting study investigated the effect of Maleic Anhydride-grafted-Polypropylene/Epoxidized Natural Rubber (PP-g-MA/ENR) as a compatibilizing agent (CA) on the properties of a 30/70 Polypropylene/Natural Rubber PP/NR blends. The effect of dynamic vulcanization with sulfur-donors (i.e.: Tetramethyl thiuram disulfide (TMTD) and 4,4 Dithiodimorpholine (DTDM)) which were used as vulcanizing agents was also reported. Several formulations of TPVs with different concentrations of CA (from 5 to 15 phr) were prepared by mixing in the molten state using a Haake Rheocord 90. The structural analysis of dual compatibilizer was examined by FTIR spectroscopy. The rheological behavior was examined using Haake Rheocord 90. The mechanical properties were determined by the tensile measurements. The dynamic mechanical thermal properties were investigated by DMA. A morphological examination was conducted using SEM Microscopy, respectively. FTIR analysis confirmed reactions between the MA group in PP-g-MA and the epoxy groups in ENR, resulting in ENR-grafted PP with an ester and acid-based linkage. The Haake plastograms revealed a proportional increase in the final mixing torque value with the increasing content of CA. The mechanical results exhibited higher values in terms of tensile strength and Young’s modulus for the TPVs containing CA compared to un-compatibilized ones. The compatibilized TPV blends exhibited a noteworthy increase in storage modulus and a notable decrease in loss tangent values with the CA concentration increased. Furthermore, the TPVs show two distinct-phase morphologies. That is, the TPV with CA showed the presence of smaller vulcanized rubber particles dispersed within the PP matrix, a phenomenon that becomes more pronounced with higher CA contents.