Abstract

Augmentation du rendement, meilleure reproductibilite du rendement et de la distribution de masse moleculaire par addition de 15 crown 5 dans le milieu dans le cas de la polymerisation par reaction de Wurtz du dichloro hexyl methyl silane et du dichloro methyl phenyl silane. Effet similaire d'un cryptand (Kryptafix 222) mais avec degradation du polymere par prolongation de la reaction

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