Abstract

The influence of highly nitrogen-doped mesoporous carbon spheres (NMCSs) (internal pore size of 5.4–16 nm) on the electrochemical response of low carbon steel (St37) in model alkaline solutions of pH 13.9 and 12.8 was studied, using Open Circuit Potential (OCP) monitoring, Electrochemical Impedance Spectroscopy (EIS) and Cyclic Voltammetry (CV). Prior to adding the NMCSs in the relevant solutions, they were characterized in the same model medium by measuring their Zeta-potential, hydrodynamic radius and particle size distribution, using dynamic light scattering (DLS) and transmission electron microscopy (TEM). In alkaline environment of pH 13.9 and 12.8, which simulates the concrete pore water of fresh and mature concrete, the DLS measurements indicated that the hydrodynamic radius of NMCSs particle varied from 296 nm to 183, respectively. According to the Zeta-potential measurements in the same solutions, the NMCSs were slightly positively charged.

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