The Effect of Nanoparticle Additives on the Lubricity of Diesel and Biodiesel Fuels

Abstract

Fuel lubricity is an essential property that ensures the longevity end efficiency of diesel CI engines. Nanomaterials have been shown to have the potential to improve lubricity in many different lubricating substances, including fuels. Moreover, the combustion process has also been shown to improve with the introduction of nanomaterials. This study investigated a series of nanoparticles, including carbon nanoplates, carbon nanotubes, aluminum oxide, zinc oxide, and cerium oxide, as lubricity-enhancing additives for selected fuels. Conventional diesel fuel and rapeseed oil methyl ester, referred to as biodiesel, were chosen as base fuels for modification. The lubricity was evaluated according to the standard test method ASTM 6079 using the HFRR tribometer. The leading lubricity indicators were the wear scar diameter, wear volume, and coefficient of friction. In addition, the worn surface analysis was performed to elucidate the lubrication mechanism. The results show that the addition of nanoparticles can improve the lubricity of both investigated fuels. However, the effect differed among nanoparticles and fuels. In summary, carbon nanotubes could be a rational choice for both fuels. In addition, zinc oxide improved the lubricity of diesel fuel, while carbon nanoplatelets and aluminum oxide nanoparticles showed improvements in the lubricity of biodiesel.