The effect of n-heptane soluble content on the composition and structure of coal tar pitch and the preparation of needle coke

Abstract

To explore the effect of n-heptane soluble (HS) content in refined coal tar pitch (RCTP) on the preparation of needle coke (NC), a series of RCTP with different HS content were prepared by the solvent method. The RCTPs were reacted at 490 °C and 0.2 MPa for 6 h to obtain green cokes (GCs), and the GCs were calcined at 1400 °C to obtain NCs. The properties of RCTPs were studied by Fourier transform infrared (FTIR) spectroscopy, 1H nuclear magnetic resonance spectrum (1H NMR), and thermogravimetric (TG) analyses. The appearance and polarized microstructure of the GCs, and the Scanning electron microscope (SEM) image, X-ray diffraction (XRD) spectroscopy, Raman spectroscopy, linear expansion coefficient, and true density of the NCs were obtained and analyzed. The results show that with the decrease of HS content, the aromaticity of RCTPs increases, and the amount and length of branched chains decrease. Mesophase structures in GCs formed by these RCTPs have different types and orientations, which leads to obvious quality differences in NCs. The NC prepared from RCTP with HS content of 15.9% (RCTP-4) has the lowest linear expansion coefficient of 0.991 × 10−6 /°C, the highest true density of 2.1195 g/cm3, better fiber structure and carbon microcrystalline structure. Therefore, the HS content should be controlled not less than 15.9%, and the TI content should not be higher than 12.6% when RCTP was prepared by solvent method.