Abstract
AbstractElimination of CH3OH from the molecular ions of the methyl esters of cyclobut‐3‐ene‐1, 2‐dicarboxylic acids under electron‐impact occurs to a much greater extent in stereoisomers having a trans configuration than in the cis analogues. Deuterium labelling shows that this process takes place via different mechanisms in the stereoisomeric esters. The abundance ratio [M CH3OH]˙+/[M CH3O]+ is suggested as the most sensitive criterion for the deduction of configuration in this system. Determination of the geometry of the cyclobutene esters by n.m.r. spectroscopy as well as by pyrolysis to corresponding isomeric muconates is also discussed.
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