Abstract

In the flotation process, the traditional dosing sequence is to add an inhibitor first, followed by a collector. However, in the sorting process of copper sulfide ore, this method of dosing does not effectively separate sulfide minerals and layered magnesium silicate minerals. In this study, the effect of adding a guar gum (as an inhibitor) and potassium amyl xanthate (as a collector, shortened as PAX) sequence to the flotation separation of pyrite and talc was investigated by micro-flotation tests, adsorption amount measurements, contact angle measurement and FT-IR analysis. The results show that the collector only adsorbs on the pyrite surface, while the inhibitor has a strong adsorption capacity on the pyrite and talc surface. Through the change of the order of the flotation reagent addition, PAX preferentially adsorbs on the pyrite surface, thereby preventing guar gum from adsorbing on the pyrite surface and achieving the selective inhibition of talc by guar gum. This study will help in understanding the molecular assembly between collectors and inhibitors to further treat complex copper sulfide nickel ore.

Highlights

  • The pre-enrichment of metal extraction in sulfide minerals is usually carried out by flotation [1]

  • The collector is used to increase the hydrophobicity of sulfide minerals, while the inhibitor improves the hydrophilicity of gangue minerals, and the flotation method is used to separate sulfide minerals and gangue minerals based on the surface wettability between them [2,3,4]

  • We investigated the selective inhibition of talc in a sulfide ore flotation system by micro-flotation tests, adsorption measurements, contact angle measurements and infrared spectrum analysis and propose a competitive adsorption model between guar gum and potassium amyl xanthate (PAX) on the solid–liquid interface

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Summary

Introduction

The pre-enrichment of metal extraction in sulfide minerals is usually carried out by flotation [1]. The collector is used to increase the hydrophobicity of sulfide minerals, while the inhibitor improves the hydrophilicity of gangue minerals, and the flotation method is used to separate sulfide minerals and gangue minerals based on the surface wettability between them [2,3,4]. Talc is a common refractory gangue mineral in sulfide ores. Due to its strong natural hydrophobicity, polysaccharides and cellulosic polymers are usually used as inhibitors to inhibit talc floating [5,6,7]. The inhibitors of organic polymers have a royalsocietypublishing.org/journal/rsos R.

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