Abstract
We present new equations of state for hard-chain fluids by employing the modified pair correlation function for hard-chain molecules at a contact diameter g(σ), which includes both inter- and intra-molecular interactions. The compressibility factor values determined using the modified pair correlation function are close to those predicted by the SAFT-D1 and SAFT-D2 theories and are in good agreement with Monte Carlo (MC) simulation data. It has also been seen that the intra-molecular interaction plays a dominating role at higher chain length and low density.
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