Abstract

High-nitrogen austenitic steels are perspective materials for an electron-beam welding and for producing of wear-resistant coatings, which can be used for application in aggressive atmospheres. The tensile behavior and fracture mechanism of high-nitrogen austenitic steel Fe-20Cr-22Mn-1.5V-0.2C-0.6N (in wt.%) after electrochemical hydrogen charging for 2, 10 and 40 hours have been investigated. Hydrogenation of steel provides a loss of yield strength, uniform elongation and tensile strength. The degradation of tensile properties becomes stronger with increase in charging duration - it occurs more intensive in specimens hydrogenated for 40 hours as compared to ones charged for 2-10 hours. Fracture analysis reveals a hydrogen-induced formation of brittle surface layers up to 6 μm thick after 40 hours of saturation. Hydrogenation changes fracture mode of steel from mixed intergranular-transgranular to mainly transgranular one.

Highlights

  • Austenitic stainless steels are frequently used materials for industrial applications due to their high ductility at cryogenic temperatures and low aggressive environment embrittlement

  • The requirements of low costs have generated an interest in replacement of nickel and use nitrogen and manganese as alloying elements

  • An indubitable advantage of such materials could be their good strength to wear combined with resistivity to degradation in aggressive atmospheres, for instance, in hydrogen

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Summary

Introduction

Austenitic stainless steels are frequently used materials for industrial applications due to their high ductility at cryogenic temperatures and low aggressive environment embrittlement. It concerns mainly AISI 300-series Cr-Ni steels [1,2,3]. The presence of expensive alloying elements – nickel – and low yield stresses limit their use. The requirements of low costs have generated an interest in replacement of nickel and use nitrogen and manganese as alloying elements. The high-nitrogen Cr-Mn steels have good mechanical properties and corrosion resistance and could be of great interest for a wide range of industrial application – in particular, for producing wear-resistant coatings or items using electron-beam welding [4] or other methods of additive technologies. An indubitable advantage of such materials could be their good strength to wear combined with resistivity to degradation in aggressive atmospheres, for instance, in hydrogen

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