The effect of hydrogen addition on methane/air explosion characteristics in a 20-L spherical device

Abstract

The addition of hydrogen to methane changes its deflagration characteristics and increases the combustion rate. However, studies on the effect of hydrogen on methane deflagration remain insufficient. Therefore, based on the CFD code GASFLOW-MPI, a four-step combustion-mechanism model was established for methane/hydrogen mixtures. The deflagration characteristics of a premixed combustible gas in a 20-L spherical device was numerically simulated using a methane/hydrogen/air equivalence ratio of 1 and hydrogen addition in the range of 0–50%; subsequently. The results were compared with experimental data. The four-step methane/hydrogen combustion-mechanism could effectively reproduce the methane/hydrogen deflagration process on considering the heat losses. With an increase in hydrogen addition, the laminar burning velocity increases, and the deflagration duration reduces. It decreases the explosion heat loss and increased the maximum deflagration pressure. Under adiabatic simulation, the maximum deflagration pressure decreased with an increase in hydrogen addition, in contrast with the experimental results. This indicates that the heat-loss effect of the methane/hydrogen/air-mixture deflagration process should not be ignored. Moreover, the heat loss during the methane/hydrogen/air-mixture deflagration was mainly caused by thermal radiation. Thus, the influence of the thermal-radiation and convective heat-transfer mechanisms should be considered in the numerical simulations of methane/hydrogen/air-mixture deflagration.