Abstract
The presence of AgCl heterogeneously doped with γ-Al 2O 3 increases the rate of dehydrohalogenation of tertiary butyl chloride significantly. The dependences of the catalytic activity on temperature, grain size and composition of the catalyst are quantitatively analyzed in terms of the concept of “heterogeneous doping”. The mechanism is interpreted in terms of Ag +-vacancy accumulation in the space charge region of silver chloride.
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