The effect of Eu 3+ concentration on the Y 2O 3 host lattice obtained from citrate precursors

Abstract

This work presents a thermal decomposition study of the precursor resin prepared from the citrate precursor along with structural features and optical properties materials composed by Y 2O 3 and Eu 3+ containing Y 2O 3 in 0.5, 3, 5 and 7 mol%. The microcrystallite sizes were estimated from the Scherrer equation. The structural and optical properties revealed that the addition of 5 mol% of Eu 3+ to the Y 2O 3 matrix gave rise to the highest relative emission intensity which was evidenced by the luminescence intensity. The lifetime of the 0.5 mol% Eu 3+-doped sample suggested two different symmetry sites for Eu 3+ ions because two different lifetime values were acquired for this sample, while for phosphors doped with 3 or 5 mol% of Eu 3+ ions only one similar lifetime was observed. When the concentration of Eu 3+ is 0.5 and 3 mol%, the luminescence intensity is weak due to the low probability of the O 2− - Eu 3+ charge transfer transition. On the other hand, when the concentration of the Eu 3+ ions is 7 mol%, a quenching effect is evidenced.