Abstract
The lifetimes of Cr(NH 3) 6 3+ and the Cr(cyclam)(NH 3) 2 + complexes, both protiated and deuterated, have been recorded in aqueous polyalcoholic and DMSO solutions in the temperature range that includes the change from a rigid glass to a fluid. A small but distinct lifetime reduction is associated with increased solvent mobility in the protiated species but not in the deuterated complex. This is interpreted to indicate that increasing anharmonicity in accepting modes enhances the nonradiative rates.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
