The Effect of Electrolyte Additives upon the Lithium Kinetics of Li-Ion Cells Containing MCMB and LiNixCo1-xO2 Electrodes and Exposed to High Temperatures

Abstract

With the intent of improving the performance of lithium-ion cells at high temperatures, we have investigated the use of a number of electrolyte additives in experimental MCMB- LixNiyCo1-yO2 cells, which were exposed to temperatures as high as 80oC. In the present work, we have evaluated the use of a number of additives, namely vinylene carbonate (VC), dimethyl acetamide (DMAc), and mono-fluoroethylene carbonate (FEC), in an electrolyte solution anticipated to perform well at warm temperature (i.e., 1.0M LiPF6 in EC+EMC (50:50 v/v %). In addition, we have explored the use of novel electrolyte additives, namely lithium oxalate and lithium tetraborate. In addition to determining the capacity and power losses at various temperatures sustained as a result of high temperature cycling (cycling performed at 60o and 80oC), the three-electrode MCMB-LixNiyCo1-yO2 cells (lithium reference) enabled us to study the impact of high temperature storage upon the SEI film characteristics.