Abstract

Pb1−xFexS nanoparticle films were grown on silicon substrates under zero, positive and negativebiasing by the chemical bath deposition technique. The grain size for films with a fixedx was observed to increase with positive biasing and decrease with negative biasing of thesubstrates. Distortion of the lattice is observed to increase and the average grain sizedecreases as the substrate bias is changed from positive through zero to negative values.The DC conductivity of the films decreases with decrease in grain size due toenhanced surface scattering. The nanoparticle films are semiconducting and show apredominance of variable range hopping of the carriers among localized states.

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