Abstract
The Pd–Ni, Pd–Co, Pd–Cr, Pd–Au, Pd–Rh, Pd–Mo and Pd–Pt fcc Pd-rich alloys have been found to exhibit large effects of cycling through the hydride phase. The effect of cycling Pd–Mo alloys is noticeable even at a composition of X Mo=0.02 whereas for Pd–Rh alloys it is not significant until X Rh>0.10. The dependence of the effect of the cycling on alloy composition will be reported here for the alloy systems Pd–Cr and Pd–Mo. The effect of cycling for a Pd–Ag alloy has also been determined. The temperature dependencies of the plateaux pressures of the cycled and the annealed alloy forms are reported for the Pd 0.95Cr 0.05 alloy.
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