The effect of concentration on the thermo-optical properties of colloidal silver nanoparticles

Abstract

The thermo-optical properties of colloidal silver nanoparticles (AgNPs) are investigated under a low power laser irradiation at 532 nm. Colloidal AgNPs are synthesized by nanosecond pulsed laser ablation of a pure silver plate in distilled water. The morphology and size of the AgNPs are determined by transmission electron microscopy. Closed Z-scan measurements reveal that nonlocal thermo-optic process is responsible for the nonlinear refractive index of colloid containing different concentrations of silver nanoparticles. The Z-scan behavior of the nanoparticle samples has been investigated based on a nonlocal thermo-optic process and it is shown that the aberrant thermal lens model is in excellent agreement with the experimental results. Z-scan measurement fits have allowed the values of nonlinear refractive index ( n 2) and thermo-optic coefficients ( dn/ dt) to be determined at different concentrations of silver nanoparticles. Large enhancement factors were measured for values of n 2 and dn/ dt of the colloids at higher silver nanoparticle volume fraction. Our results suggest that nonlocal thermal nonlinear processes will play an important role in the development of photonic applications involving metal nanoparticle colloids.