Abstract

The purpose of the study is to assess the influence of SiC particles and heat treatment on the wear behaviour of Ni–P coatings when in contact with a 100Cr6 steel. Addition of reinforcing particles and heat treatment are two common methods to increase Ni–P hardness. Ball-on-disc wear tests coupled with SEM investigations were used to compare as-plated and heat-treated coatings, both pure and composite ones, and to evaluate the wear mechanisms. In the as-plated coatings, the presence of SiC particles determined higher friction coefficient and wear rate than the pure Ni–P coatings, despite the limited increase in hardness, of about 15%. The effect of SiC particles was shown in combination with heat treatment. The maximum hardness in pure Ni–P coating was achieved by heating at 400 °C for 1 h while for composite coatings heating for 2 h at 360 °C was sufficient to obtain the maximum hardness. The difference between the friction coefficient of composite and pure coatings was disclosed by heating at 300 °C for 2 h. In other cases, the coefficient of friction (COF) stabilised at similar values. The wear mechanisms involved were mainly abrasion and tribo-oxidation, with the formation of lubricant Fe oxides produced at the counterpart.

Highlights

  • Ni–P coatings have been mainly obtained through electroless plating [2]

  • The present study aims to evaluate the effect of SiC particles in combination with different heat treatment conditions on the wear behaviour of Ni–P

  • The Ni–P coating (Figure 4a) had a shiny appearance while the Ni–P/SiC was a matt coating (Figure 4b). This difference was attributed to the presence of SiC particles, which increased the surface roughness of the coatings and changed the reflection of the light

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Summary

Introduction

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. Coatings are often applied to industrial components to enhance the durability of materials in abrasive conditions or corrosive environments. Nickel-phosphorous (Ni–P) alloys are one of the most applied alternatives for applications such as aerospace, electronics, machinery, automotive, oil and gas [1,2,3,4]. Ni–P coatings have been mainly obtained through electroless plating [2]. Due to the low overall speed (the deposition rate is only a few micrometres per hour) and continuous maintenance, electroplating could be a valid alternative [3]. The properties of Ni–P coatings depend on their phosphorus (P) content

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