Abstract
The influence of 1.6 to 14.5mol% water, 1.1 to 18.3mol% fluorine (F) and 0.5 to 1.4mol% chlorine (Cl) on the viscosity of peralkaline and peraluminous Na2O–CaO–Al2O3–SiO2 melts as a model system for phonolites was studied with the micropenetration method within the range of 109 to 1013Pas. Water and F alone and combined decrease viscosity non-linearly. With increasing F and water concentration the further addition of F and water becomes less effective in decreasing viscosity. Water decreases the viscosity of peraluminous melts more strongly than that of peralkaline melts. In the halogen-free peraluminous sample 5mol% water decreases Tg12 (the temperature where the viscosity=1012Pas) by 259±5K, while in the halogen-free peralkaline sample 5mol% water decreases Tg12 by 189±5K. Fluorine (on a mol% basis) decreases the viscosity of Na2O–CaO–Al2O3–SiO2 melts less than water. In the peraluminous melts the addition of 5mol% F decreases Tg12 by ~95K. In the peralkaline melt 5mol% F decreases Tg12 by ~30K. However, a significant decrease in Tg12 was only observed up to a F concentration of 1.9mol% F, another sample with 6.2mol% F showed no further decrease of Tg12. In all hydrous peraluminous and peralkaline samples that contain F alone or combined with Cl, the decrease of viscosity due to the addition of water is smaller than in the halogen-free samples. In a peraluminous melt with 18.3mol% F the addition of 5mol% water decreases Tg12 by about 152±5K compared to the dry melt. In a peralkaline melt with 1.9mol% F the addition of 5mol% water decreases Tg12 by about 146±5K compared to the dry melt. In both cases this is significantly less than for the halogen-free samples. In peralkaline melts Cl has no influence on the decrease in viscosity upon the addition of water. The effects of water and Cl on viscosity are independent of each other and add together. The effects of water and F on viscosity are not independent, which could be, in the case of the peralkaline samples related to changes in F speciation due to the presence of water.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
