Abstract
The conductivity of rubidium nitrate doped with barium nitrate in studied aimed at inserting cationic vacancies into the rubidium nitrate lattice. The conductivity of the RbNO3-II phase is shown to increase in proportion with the dopant concentration, which points to the formation of solid solutions and the increase in the concentration of cationic vacancies. The solubility of barium nitrate in phases RbNO3-III and IV is low; hence, the conductivity of these phases is virtually independent of the dopant content. The insignificant increase in conductivity of phase IV in the sample containing the high concentration of barium nitrate (1 mol %) is probably associated with the effect of the heterogeneous Ba(NO3)2.
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