The effect of calcium on the properties of SmBa1−xCaxCoCuO5+δ as a cathode material for intermediate-temperature solid oxide fuel cells

Abstract

The effect of calcium on the properties of SmBa1–xCaxCoCuO5+δ (x=0.0–0.3) as a cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFCs) is evaluated systematically. Samples exhibit a highly crystalline double perovskite phase, and their cell volumes decrease as x is changed from 0.0 to 0.3. The oxygen content and average thermal expansion coefficient (TEC) of SmBa1–xCaxCoCuO5+δ decreases as the calcium content increased. An average TEC of as low as 15.3×10−6°C−1 is obtained for SmBa0.7Ca0.3CoCuO5+δ. The area specific resistances at 700°C decrease by approximately 50% when the calcium content is increased from x=0.0 (0.173Ωcm2) to x=0.3 (0.086Ωcm2). The maximum power densities of SmBa1−xCaxCoCuO5+δ-based single cells at 800°C increase from 635mWcm−2 (x=0.0) to 939mWcm−2 (x=0.3).