Abstract

Further work on the Banker-Vankataraman transformation in the indane series is described (see Nowlan, Slavin, and Wheeler, J., 1950, 340). A study of this reaction applied to vic,-benzoloxytetrahydroacetonaphthones support the view that the 1 : 2-bond in 5 : 6 : 7 : 8-tetrahydronaphthalene derivatives has a higher order than the 2 : 3-bond. The existance of steric strain in the acetyl group 5 : 6 : 7: 8- tetrahydro-2-hydroxy-1-acetonaphthone is demonstrated and its effects are discussed.

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