The effect of B site doping of Nb5+ and aging process on the properties of BNKT-BT lead-free piezoelectric ceramics

Abstract

This research explored the influence of Nb 5+ doping on the electrical properties and microstructure of [0.852(Bi 0.5 Na 0.5 )-0.11(Bi 0.5 K 0.5 )-0.038Ba]Ti (1- x ) Nb x O 3 (designated as BNKT-BT). The BNKT-BT samples were fabricated and the XRD results showed that the doping of Nb 5+ ions induced a transformation from the coexistence of both rhombohedral and tetragonal phase to a single pseudo cubic phase. Also, the doping of Nb 5+ ions caused the temperature of ferroelectric state-ergodic relaxor state transition to decrease below the room temperature (RT). The SEM observations showed that the Nb 5+ doping had a minor effect on the grain size of BNKT-BT samples. In addition, the samples achieved a large electrostrain of 0.43% ( d * 33 = S max / E max = 614 pm/V) under 7 kV/mm at RT. Moreover, the aging process employed at 80 °C for two weeks in air could effectively increase the electrostrain from 0.38% to 0.41% under 6 kV/mm ( d * 33 = 683 pm/V) and reduce the strain hysteresis from 57% to 34%. These results indicated that the B site doping, combined with the aging process, could provide an effective way to enhance the electrostrain performance of lead-free piezoelectric ceramics. • Niobium ions as dopants can effectively destroy the long-range ferroelectric order of the BNKT-BT-based ceramics. • At room temperature, with the addition of niobium ions, the samples change from ferroelectric state to ergodic relaxed state. • Niobium ions doping and the aging process provide an effective means for the development of practical BNT-based ceramics.