Abstract
The effect of adsorption on the EELS of the tungsten (100) surface plane, for loss energies in the range of 2–25 eV, is investigated for a series of adsorbates (i.e. O 2, N 2, NO, CO and H 2). Low-lying sharp structures observed in the energy loss spectra seem to be associated with prominent structures in the local surface density of states. A growth of a peak at a loss energy of about 7.5 eV, observed after exposing the surface to any one of the gases studied, is attributed to the breakdown of optic-like selection rules by the adsorption process. The effect of adsorption on the various surface plasmon peaks seems to be adsorbate-specific.
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