The Effect of Additives on the Hydrothermal Synthesis and Thermochromic Performance of Monoclinic Vanadium Dioxide Powder

Abstract

Monoclinic vanadium dioxide VO2(M) is a well-known thermochromic material, with its critical transition temperature (68 °C) being the closest to room temperature (RT). Among the variety of grown methods, hydrothermal synthesis is a simple and cost-effective technique to grow thermochromic VO2 in the form of powder. In the present work, VO2 nanoparticles were prepared by hydrothermal synthesis in mild conditions, followed by a thermal annealing process at 700 °C under nitrogen flow for two hours. Vanadium pentoxide (V2O5) was used as the vanadium precursor, while two different reducing agents, namely oxalic and succinic acid, were employed for the reduction of V2O5 to VO2. Additionally, urea as well as thiourea were used as additives, in order to investigate their effects on the thermochromic performance of VO2. As a result, the VO2 (M) phase was obtained after annealing the crystalline powder, grown hydrothermally using oxalic acid and thiourea as a reducing agent and additive, respectively. This synthesis had a high yield of 90%, and led to a VO2(M) powder of high purity and crystallinity. In particular, the VO2 (M) nanoparticles had an average crystallite size of approximately 45 nm, a critical transition temperature of approximately 68 °C and a hysteresis width of 11 °C.