Abstract

The effect has been observed of small additions of sodium oleyl- p-anisidinesulphonate on the rate of extraction of iodine from aqueous solutions with carbon tetrachloride in an agitated extractor. The results have been analysed by the method of H ixon and S mith [2]. The time required for extracting 90% of the extractable iodine from the aqueous phase increased with the concentration of surface-active agent to a maximum about 70% above the original value at 3 × 10 −5 g/100 ml aqueous solution, and fell on further additions far below the original value. The H ixon lines were curved for the larger additions of surface active agent, indicating a gradual increase in interfacial area.

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