The effect of a Lorentz-force-driven rotating flow on the detachment of gas bubbles from the electrode surface

Abstract

The enhanced bubble detachment in water electrolysis due to Lorentz-forces is discussed for the case of mainly parallel electric and magnetic fields. Experiments and numerical simulations were carried out to assess the velocity and pressure distribution around single rigid spheres mimicking electrolytic bubbles on a horizontal electrode in the presence of a vertical magnetic field. Astigmatism particle tracking velocimetry delivered the three-dimensional flow field and a finite volume method was used for the computations. Formerly it was assumed that the flow-induced pressure decrease at the bubble's top caused the earlier detachment under magnetic field action. However, the experimental and numerical results obtained here demonstrate that this pressure decrease is too weak as to effectively change the detachment process. Finally, an alternative explanation for the observed bubble behavior is suggested: it might result from the comparatively strong global flow generated by the additive effect of a group of bubbles.