Abstract
In this paper was performed an E.S.R. study on copper ions in water and ammoniacal solutions to put in the light and H-D isotope effect which appears in the shape and the width modifications of spectral lines. The isotope effect is different in terms of the paramagnetic ion concentration at room and liquid nitrogen temperature. These effects were explaines by the isotopic modifications of dipolar interactions among copper ions and between copper ions and ligand nuclei and also by the isotopic modifications of crystalline field in frozen solutions.
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