Abstract
Vibrational and rotational energy in the CN fragment has been investigated for the dissociations H(D)CN → H(D) + CN(B 2Σ +) at several wavelengths in the vacuum ultraviolet. A simple global model has been applied to these results to elucidate features of the dissociative potential surfaces. A comparison of these results with earlier theoretical predictions demonstrated that the disposal of vibrational energy in these reactions is crucially dependent on Franck-Condon factors, and is relatively insensitive to final state interactions.
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