Abstract
The ionization of HCl molecules by thermal energy collisions with metastable Ne * atoms has been studied experimentally and theoretically. The integral elastic cross sections have been measured and analyzed, together with the total ionization cross sections, to obtain an optical potential able to describe the collision dynamics of the neutral reactants. The relative cross sections for NeH + and NeD + production in Ne * -HCl or DCl have been measured as a function of the collision energy. A theoretical calculation of the potential energy for the reactive Ne + HCl + (A)→NeH + +Cl system has been performed by SCF, CI, and CASSCF methods
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