Abstract

The growth kinetics of the discontinuous coarsening reactions in the PbCd and the ZnCd lamellar eutectic alloys have been studied at temperatures ranging from 353 to 489 K by scanning and transmission electron microscopy. In the PbCd system discontinuous coarsening were observed at all ageing temperatures whereas in the ZnCd system it was only observed between 396 and 433 K. The lamellar spacing of the discontinuous cells in the PbCd system were found to increase with increasing temperature, pass through a maximum and then decrease. The kinetics of the reaction are compared with the existing data. The analysis of the growth kinetics suggests that the reaction is controlled by grain boundary diffusion. The reported data on discontinuous coarsening are analysed by using Livingston and Cahn's [ Acta metall. 22, 495 (1974)] and Fournelle's [ Acta metall. 27, 1147 (1979)] models. The applicability of the models to different systems is discussed.

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