Abstract
In this mini-review, synthetic methods for biaryls and heterobiaryls interconnecting the directed ortho metalation (DoM) reaction with Corriu–Kumada, Negishi, Suzuki–Miyaura and, less, Stille cross coupling reactions are presented from perspectives of development of new reaction parameters (Suzuki–Miyaura: Schemes 4–7), new cross coupling partners (Corriu–Kumada: Schemes 9 and 11), and comprehensive evaluation ( Schemes 12 and 13). Recent work on the application of these protocols to indole derivatives ( Schemes 16–18), dibenzopyranones ( Scheme 19), aza- and isoazacoumestans ( Scheme 20), and kinamycin antibiotics ( Scheme 21) is described.
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