Abstract

The A tilde formed from X tilde transition in ammonia is investigated by direct ultraviolet absorption spectroscopy of samples cooled in supersonic jet expansions. Franck-Condon factors are reported here for this transition of NH/sub 3/ and ND/sub 3/: they are considerably different from those available from room-temperature data. The spectra are discussed in light of models available for the A state ammonia.

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