Abstract
The electrochemical oxidation of anodic Zn, Cd or Hg (M) into acetonitrile solutions of RSH (or R 2S 2) gives the corresponding M(SR) 2 compounds in high yield. The mechanism of the electrochemical reactions is discussed. The insolubility, and the far infrared spectra (500–50 cm −1), are compatible with a polymeric structure for M(SR) 2 in the solid state.
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