Abstract
Abstract : It is shown that the direct correlation function of a mixture or hard ions in the mean spherical approximation of Hiroike, (MSA) can be expressed in terms of overlap functions of charged spherical spherical shells. In particular, if the system has a mixture of pairs of ions of equal size and opposite charge, then the MSA direct correlation function is given by the electrostatic energy of a pair of charged function is given by the electrostatic energy of a pair of charged shells, of radius equal to the radius of the hard ion plus 1/21. As in the theory of Rosenfeld this direct correlation function can be derived from a free energy functional, and a simple extension to non-uniform systems is given.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
