Abstract

Hierarchical ultrathin ZSM-5 zeolite samples with controllable crystal growth directions were realized by designing bifunctional soft templates with different hydrophobic alkyl chain groups. MFI-type crystal growth along the a-c plane and stacking along the b-axis could be controlled to form nanowires of ZSM-5, which exhibited better catalytic activity for phenol hydroxylation than nanosheets of ZSM-5.

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