Abstract
The technique described by Feldberg5 for the digital simulation of electrode reactions has found wide application in recent years because of its accuracy, simplicity and applicability to many electrochemical experiments and systems involving complex chemistry. There are, however, experiments which may only be simulated by this technique by totally extravagant use of a computer. In this paper, we describe several modified simulation techniques, based on the use of a space grid of variable dimensions and/or an implicit solution which are of equally general applicability but which reduce computation times by a factor of a hundred without significant loss of accuracy. A potential step experiment on a catalytic system has been simulated by each of the techniques and the computation times and accuracies are compared.
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