Abstract

A critical study of the crystal forms of diamond from various sources demonstrates that the symmetry of the structure may be either that of Class 32 or Class 31, in other words that the structure may be either centrosymmetric or non-centrosymmetric. Diamonds belonging to Class 31 may however exhibit a pseudo-octahedral symmetry of external form by reason of the interpenetration of oppositely directed structures having the lower symmetry. The existence of diamond with two differing structures provides an insight into the many remarkable properties of this material,viz., the striking differences observed in the infra-red absorption spectra, differences in transparency to ultra-violet rays, the differences in the intensity of their X-ray reflections and the variations in the intensity and colour of the luminescence exhibited by them.

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