The devitrification kinetics of silica powder heat-treated in different conditions

Abstract

In the present paper, the devitrification kinetics of silica powder heat-treated in air and in nitrogen were investigated. The heat-treated powders were confirmed to partially crystallize into cristobalite by X-ray diffraction analysis. The devitrification kinetics data of silica powder fitted the Avrami equation very well. The measured value of n was ascertained to be 1.63 and 1.60 when the silica powder was heat-treated in air and in nitrogen, respectively, corresponding to activation energies of 408kJ/mol and 529kJ/mol, respectively. The effect of phenolic resin-derived carbon on crystallization of silica powder was also studied. By adding phenolic resin into silica powder, the devitrification of silica powder was fully restrained up to 1500°C in flowing nitrogen. High concentrations of oxygen vacancies may retard the nucleation of cristobalite on the surface of silica powder. Phenolic resin-derived pyrolysis carbon restrained the nucleation of cristobalite, because it prevented the reactions of oxygen vacancies with H2O and O2 molecules.