Abstract
This work presents a detailed investigation for the effect of Y2O3 and Ni additions on the densification behavior, microstructural evolution and mechanical properties of a WC-Co-TaC-NbC composite. With the aim of obtaining WC-based composites with improved fracture toughness, to be used in severe conditions of high-temperature deformation, different concentrations of Y2O3 were incorporated with and without 5 wt% Ni addition. The consolidated composites were characterized using density measurement, XRD, SEM, hardness, fracture toughness, transverse rupture strength and compression testing. Fully dense composites were obtained through the applied consolidation regime of cold compaction and sintering at 1450 °C for 1.5 h under vacuum with a relative density up to 97%. The addition of 2.5 wt% Y2O3 to the base WC composite increased the relative density and then slightly decreased with the increase of the Y2O3 content. The addition of 5 wt% Ni to the base composites significantly increased the relative density to 97%. The XRD results indicated the existence of the Co3W3C η-phase after sintering, and the intensity of its peaks was reduced with the addition of 5 wt% Ni. The microstructure of the consolidated composites consisted of three phases: WC, Co3W3C and Y2O3. The area fraction of the Y2O3 phase increased as its weight fraction increased. In terms of the fracture toughness, the transverse-rupture strength (TRS) and the compressive strength were significantly improved by the addition of 5 wt% Ni with the 2.5 wt% Y2O3. Accordingly, this composition was used to manufacture the tools for the friction stir welding of the high-softening-temperature materials, which was successfully used for 25 plunges and about 500 cm of butt joints in nickel-based and carbon–steel alloys.
Highlights
Hard metals or cemented carbides are composite materials with one or more hard but relatively brittle carbide phases that are bonded together by a soft and ductile binder such as Co, Ni and Fe [1]
Qing et al [28] investigated the effect of Y2O3 on the microstructure and mechanical properties of tungsten carbide with 12 wt% cobalt prepared using a solid–liquid doping method and spark plasma sintering (SPS)
They reported that the existence of Y2O3 hindered the growth of WC grains and the composite sample with 1.3 wt% Y2O3 possessed maximum hardness and fracture toughness measured at 1446.9 HV and 11.9 MPa·m1/2
Summary
Hard metals or cemented carbides are composite materials with one or more hard but relatively brittle carbide phases that are bonded together by a soft and ductile binder such as Co, Ni and Fe [1]. Qing et al [28] investigated the effect of Y2O3 on the microstructure and mechanical properties of tungsten carbide with 12 wt% cobalt prepared using a solid–liquid doping method and SPS They reported that the existence of Y2O3 hindered the growth of WC grains and the composite sample with 1.3 wt% Y2O3 possessed maximum hardness and fracture toughness measured at 1446.9 HV and 11.9 MPa·m1/2. Yang et al [29] prepared WC-8 Co composite powders doped with Y2O3 by the wet chemical method and conducted the consolidation using by SPS at 1200 ◦C, 1250 ◦C and 1300 ◦C They reported that the comprehensive performance of WC-8%Co cemented carbide doped with Y2O3 was best at the sintering temperature of 1250 ◦C, with a hardness of 19.64 GPa and a fracture toughness of 11.97 MPa m1/2. SSEEMM mmiiccrrooggrraapphhssfofrorthtehme moroprhpohlooglyogoyf tohfetrhaewrapwowpdoewrsd. (ear)sW. (Ca)-CWo-CN-CbCo--TNabCC, (-bT)aC, (b) Y2O3 anYd2O(3ca)nNdi.(c) Ni
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