Abstract
Ground Tyre Rubber (GTR) from scrap automotive and truck tyres was blended with Waste Polypropylene (WPP) from injection moulded products to prepare GTR/WPP blends . The blends were prepared in a Haake Rheocord PolyLab System, operating at 180 0 C and 30 rpm for 8 minutes. The degree of crystallinity of the WPP in the GTR/WPP blend was found to be unchanged up to a GTR level of 60 % by weight. Crystalline melting point and re-crystallization temperature showed a significant decrease with GTR content. Optical micrograph of the blends containing up to 60 wt% GTR showed a similar morphology, in which the GTR was dispersed in a continuous WPP phase. The GTR dispersed phase grew in size with GTR content until at 70 wt%, it changed to a continuous phase. However, all blends showed a mixture of cohesive, adhesive and ductile failures. The response to tensile loading ranged from a ductile plastic response with WPP-rich blends to a high extension-rubbery response with GTR-rich blends. Under impact loads, brittle fracture occurred in blends containing up to 40 wt% GTR, with ductile fracture thereafter. Hardness, tensile strength, secant modulus at 7% strain and tear resistance decreased with increase in GTR content, while % elongation at break and impact failure energy increased.
Highlights
Polymer waste accounts for a major share of all waste materials collected in the world today
This paper presents the preliminary work on the processing and development of blends containing waste materials from the polymer industry for use in products such as roof slates, sports surfaces and industrial belts
The initial work was focused on the preparation of simple rubber-thermoplastic blends from ground tyre rubber and waste polypropylene, studies of their morphologies, physical property variations with composition and the identification of suitable blends for commercial applications
Summary
Polymer waste accounts for a major share of all waste materials collected in the world today. Polymer waste can be either disposed of in a safe manner or be recycled and reused[1, 2] These materials can be utilised to generate energy or to recover fuels[3, 4] and valuable chemicals, which are feedstock for other industries[5, 6]. Rubber toughened thermoplastics which exhibit flexible and high impact properties can be used as economical alternatives for ordinary plastic materials. The market for such materials has grown dramatically because of the ability to recycle and reprocess them using conventional thermoplastic machinery . The initial work was focused on the preparation of simple rubber-thermoplastic blends from ground tyre rubber and waste polypropylene, studies of their morphologies, physical property variations with composition and the identification of suitable blends for commercial applications
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