Abstract

Here, we describe a nanocomposite polymer electrolyte prepared using a solution casting technique.

Highlights

  • Solid polymer electrolytes (SPEs) are prepared by complexing polymers with metal salts

  • In order to assess the performance of the nanocomposite polymer electrolytes (NPEs), the sample was fabricated in an fluorine-doped tin oxide (FTO)/TiO2-dye/Polyethylene oxide (PEO)–lithium iodide (LI)–0.6 wt% NCC/I2/Pt dye-sensitized solar cell (DSSC) and tested under illumination of light

  • Free PEO–LI standing films with various NCC weight ratios were successfully prepared via performing a solution casting technique

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Summary

Introduction

Solid polymer electrolytes (SPEs) are prepared by complexing polymers with metal salts. The diffusion of electrons in the conduction band of TiO2 is considered to occur via an ambipolar diffusion mechanism.[29–31] In these studies, the lithium cation (Li+) was used due to the above considerations and due to its small cationic radius allowing it to penetrate into the dye-coated TiO2 film and form ambipolar Li+–eÀ pairs with the electrons in the conduction band of TiO2. The lithium cation (Li+) was used due to the above considerations and due to its small cationic radius allowing it to penetrate into the dye-coated TiO2 film and form ambipolar Li+–eÀ pairs with the electrons in the conduction band of TiO2 This feature has been indicated to increase the transport speed of electrons in the TiO2 network and enhance current density ( JSC) levels of the DSSCs.[32,33]. The potential practicality of the polymer electrolyte in DSSCs was investigated

Materials
Preparation of NCC and NPE
Preparation of NPE films
Characterization techniques
DSSC fabrication and current density–voltage measurements
X-Ray diffraction (XRD)
FTIR analysis
Electrochemical analysis
DSSC performance
Conclusions
Full Text
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