Abstract
The selective synthesis of heteroleptic (heteronuclear) sandwich-type lanthanide phthalocyanines has been accomplished. Double-decker complexes BuPcLnPc, and BuPcLnPc Cl (Ln = Lu, Eu; BuPc = 2,3,9,10,16,17,23,24-octabutylphthalocyaninate; Pc = phthalocyaninate, ClPc = 2,3,9,10,16,17,23,24-octachlorophthalocyaninate) were obtained in good yields by a direct interaction of metal-free ligand BuPcH 2 with the monophthalocyanines PcLnOAc or ClPcLnOAc. Heteronuclear triple-decker phthalocyanines PcEu RPcLu RPc, ClPcEu RPcLu RPc and BuPcEu RPcLu RPc ( RPc = BuPc, tBu Pc; tBu Pc = 2(3),9(10),16(17),23(24)-tetra- tert-butylphthalocyaninate) were obtained from the corresponding mono-(PcEuOAc, ClPcEuOAc, BuPcEuOAc) and bisphthalocyanines ( RPc 2Lu) under similar conditions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
