Abstract

Polymer gel sensors on 96-well plates were successfully used to detect four different multi-explosives, including 2,4,6-trinitrotoluene (TNT), 2,4-dinitrotoluene (DNT), nitrite, and perchlorate. The products of reactions between the explosives and the polymer gel sensors were digitally captured, and the images were analyzed by a developed Red–Green–Blue (RGB) analyzer program on a notebook computer. RGB color analysis provided the basic color data of the reaction products for the quantification of the explosives. The results provided good linear range, sensitivity, limit of detection, limit of quantitation, specificity, interference tolerance, and recovery. The method demonstrated great potential to detect explosives by colorimetric analysis of digital images of samples on 96-well plates. It is possible to apply the proposed method for quantitative on-site field screening of multi-explosives.

Highlights

  • Explosions can inflict serious, even life-threatening injuries on many people at the same time [1]

  • The increased controls placed on commercial and military explosives has made the use of improvised explosive devices (IEDs) more prevalent

  • The determination of multi-explosives detected with specific polymer gel sensors on 96-well plates was based on the colorimetric analysis of digital images

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Summary

Introduction

Explosions can inflict serious, even life-threatening injuries on many people at the same time [1]. Explosions cause damage in several different ways: by the blast wave, the shock wave, heat, fragmentation, or the blast wind. Explosives are commonly classified as high and low explosives, according to the type and velocity of the reaction involved [2]. Homemade explosive devices or improvised explosive devices (IEDs) are simple to make using widely accessible materials. The increased controls placed on commercial and military explosives has made the use of IEDs more prevalent. IEDs can vary widely in size; most have at least four components: a power source, a main charge, an initiator, and a switch

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